The crystal structure of 1-(2-thiazolylazo)-2-naphtholatodiaquacopper(II) perchlorate.

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概要

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• The crystal structure of 1-(2-thiazolylazo)-2-naphtholatodiaquacopper(II) perchlorate, [Cu<SUP>II</SUP>(TAN)(H<SUB>2</SUB>O)<SUB>2</SUB>]-ClO<SUB>4</SUB>, has been determined from three-dimensional X-ray data collected by counter methods. The crystals are monoclinic, with the space group P2<SUB>1</SUB>/c; <I>a</I>=13.481(4), <I>b</I>=8.060(4), <I>c</I>=15.307(7) Å, β=95.58(4)°, and <I>Z</I>=4. The structure was refined to an <I>R</I> value of 0.086 for 952 non-zero reflections. The copper atom is five-coordinated and has a distorted square-pyramidal environment. The 1-(2-thiazolylazo)-2-naphtholato group (TAN) acts as a terdentate ligand, the phenolic oxygen, the azo nitrogen and the thiazole nitrogen atoms being coordinated to the copper atom to give two five-membered chelate rings. The remaining two positions are occupied by water molecules.

• 公益社団法人 日本化学会の論文

著者

• KURAHASHI Masayasu

  National Chemical Laboratory for Industry

• Kawase Akira

  National Research Institute for Metals

• Kawase Akira

  National Chemical Laboratory for Industry

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