A study of ion-solvent interaction of tetraalkylammonium and common alkali metal ions in ethylene carbonate from electrolytic conductance data.

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Ion-solvent interaction in solutions of some tetraalkylammonium and common alkali metal iodides in ethylene carbonate, from the point of view, of electrical conductance and the derived Walden product, has been examined in this communication. The Debye-Hückel-Onsager equation appears to hold good for all the salts in the temperature and concentration range studied here. Dependence of the Walden product on temperature and radius of cation reveals that the R4N+ ions do not interact appreciably with the solvent but Li+, Na+, K+, and Rb+ ions appear to be solvated.
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