On the diffusivity of nonelectrolytes in infinitely dilute solution.
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概要
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The validity of the plot, isoviscous diffusion coefficient <I>D</I><SUB>1</SUB>η<SUB>2</SUB> <I>vs.</I> molar volume <I>V</I><SUB>2</SUB>, where <I>D</I><SUB>1</SUB> is the diffusion coefficient of solute at infinite dilution, η<SUB>2</SUB> the viscosity coefficient of solvent, and <I>V</I><SUB>2</SUB> the molar volume of solvent, proposed by Hammond and Stokes for carbon tetrachloride, was examined and confirmed with several solutes. General features of the behavior of diffusivity in dilute solution are discussed in terms of solvent association, complex formation and other factors. The experimental results for iodine are given.
- 公益社団法人 日本化学会の論文
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