Solvolysis in carboxamides. III. Solvolysis rates of 1-adamantyl bromide and tosylate, 2-adamantyl tosylate, and t-butyl chloride in carboxamides.

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概要

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• Rate constants for the solvolysis of 1-adamantyl bromide and tosylate, 2-adamantyl tosylate, and <I>t</I>-butyl chloride in the four carboxamide solvents, <I>i. e.</I>, <I>N</I>,<I>N</I>-dimethylacetamide, <I>N</I>,<I>N</I>-dimethylformamide, <I>N</I>-methylacetamide, and <I>N</I>-methylformamide, have been determined. The role of the carboxamides as solvolytic solvents has been discussed on the basis of linear free-energy relationship.

• 公益社団法人 日本化学会の論文

著者

• Moriwake Toshio

  Department of Synthetics Chemistry, School of Engineering, Okayama University

関連論文

• Solvolysis in carboxamides. II. Solvolytic elimination of 7.BETA.-methylbicyclo[3.3.1]non-3.BETA.-yl tosylate in carboxamides.
• Solvolysis in carboxamides. V. Solvolytic elimination of threo-1-methyl-2-phenylpropyl brosylate in N,N-dimethylacetamide. Kinetic, product, and deuterium tracer studies.
• Solvolysis in carboxamides. VII. Carboxamide solvolysis of threo-2-aryl-1-methylpropyl brosylates. Reactivity-selectivity relationships as a mechanistic probe.
• Solvolysis in carboxamides. III. Solvolysis rates of 1-adamantyl bromide and tosylate, 2-adamantyl tosylate, and t-butyl chloride in carboxamides.

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