The Electrical Conduction of the <I>p</I>-Phenylenediamine Iodine Complex
スポンサーリンク
概要
- 論文の詳細を見る
In the case of a complex of <I>p</I>-phenylenediamine with iodine, a nonstoichiometrical composition has been established; the minimum values for both the magnitude and the temperature dependence of resistivity exist on the complex the coordination number of which is around 0.8. On the other hand, the maximum value of the apparent density appears in the vicinity of 1.0.<BR>In comparison with the complex of <I>p</I>-phenylenediamine-iodine and that of <I>p</I>-phenylenediamine-chloranil, even though the redox potential of chloranil is larger than that of iodine, the resistivity and the activation energy of the <I>p</I>-phenylenediamine-iodine system are smaller than those of the chloranil complex.
- 社団法人 日本化学会の論文
著者
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Nishizaki Shun-ichiro
Mitsubishi Electric Corporation Research Laboratory
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Nishizaki S.
Mitsubishi Electric Corporation Research Laboratory
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Kusakawa Hideaki
Mitsubishi Electric Corporation Research Laboratory