茶のアミノ酸に関する研究-1-
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概要
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Natural theanine was first synthesized by the authors, and was proved to be L-glutamic acid γ-ethylamide (II). In these days the author studied a new synthetic method which was a modification of the LICHTENSTEIN's method, i.e. L-pyrrolidone carboxylic acid (I) was sealed with pure ethylamine, instead of its aqueous solution. This method was as follows: By using this method, the author could synthesize theanine with 35.6% of the theoretical yield. Theanine obtained here has mp. 217° (decompose) and [α] 24Hg=+23.5. The mixture with natural theanine (mp. 217°) shows no depression of melting point.
- 社団法人 日本農芸化学会の論文