ポリ塩化ビニル樹脂の帯電防止剤としてのポリオキシエチレンアルキルアミン金属錯塩

概要

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Several metal complexes were sythesized by the reaction of polyoxyethylene alkylamine with chlorides of some metals, such as calcium, barium, magnecium, zinc, tin, manganees, copper, nickel, cobalt, iron. Another metal complexes were prepared from some inorganic and organic acid salts. These salts used were sulfate, nitrate, perchlorate, p-toluene sulfonate, benzoate, phthalate, maleate, sebacate and several fatty carboxylates. The properties of these metal complexes as internal antistatic agents for PVC were evaluated by measuring the frictional charge generated and charge decay by Rotary Static Tester, and these were found to be effective antistatic agents with good thermal stability. The most effective range of the moles of ethylene oxide added was about 10 to 15. Metal complexes made from metallic chloride were generally good antistatic agents, and among the fatty acid salts, calcium and cupric acetate gave the most effective complexes. Organic acid metal complexes, except p-toluene sulfonic acid salt, were less effective.
日本油化学会の論文