ベンゼンの赤外吸牧強度と溶媒効果 (第1報)

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概要

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• The intensity of C-D streching absorption band in monodeutrobenzene is measured in various solvents, and the relations between the intensity and the bulk properties (dielectric constant and refractive index) of the solvents are investigated.<BR>The solvents used are found devided into two groups: in the one, the intesity decreases as tee dielectric constant of the solvent becomes larger, in the the other this effect is reversed.It is also shown that the former group satisfies Buckinghams theory concerning diatomic molecules.The quantity μ<SUP>l</SUP>, /μ<SUP>l</SUP> is found negative in the former group.

• 社団法人 日本分光学会の論文

著者

• 石田 和義

  丸善石油株式会社中央研究所

• 滝野 彰彦

  丸善石油株式会社中央研究所

• 松井 靖

  丸善石油株式会社中央研究所

関連論文

• ベンゼンの赤外吸牧強度と溶媒効果 (第1報)
• S.W. Polarographic Determination of Mercaptan Compounds and Free Sulfur in Petroleum Naphtha

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