含フッ素アミノ酸の酵素合成
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概要
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Some amino acids are synthesized effectively by enzymatic reactions. These enzymatic reactions are also applicable to the synthesis of optically active fluorine-containing amino acids by the use of corresponding fluorine-containing precursors.<BR>This paper describes the following enzymatic reactions. 1) Synthesis of fluorine-containing phenylalanines by transamination of corresponding fluorine-containing phenylpyruvic acids, by phenylalanine ammonia-lyase reaction of fluorine-containing <I>t</I>-cinnamic acids, and by acylase reaction of fluorine-containing <I>N</I>-acetyl phenylalanines, 2) synthesis of fluorotyrosines by β-tyrosinase starting from fluorophenols and serine, 3) synthesis of fluorotryptophan by tryptophanase starting from fluoroindole and serine.
- 社団法人 有機合成化学協会の論文