有機反応における溶媒の働き方について
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概要
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This review article discusses the mode and probe of the solvent participation in the organic reactions. Emphases are given to the elementary rate processes and also to the indirect participation of solvent clusters. Discussions are given in the order : 1) General background. 2) Empirical LFER with solvent parameters. 3) Thermochemical approach. 4) Information from the gas-phase reactions. 5) Significance of the solvent molecule reorganization during the activation process of the liquid-phase reactions. 6) Examples and the mode of solvent participation. This review does not aim the comprehensive coverage of the current awareness of the solvent effect but tries to point out the importance of the insight of the microscopic view of the total solution system where the reaction is taking place.
- 社団法人 有機合成化学協会の論文