不斉認識機能を有する錯体触媒--錯体の高次機能化による酵素へのアプロ-チ (有機合成における金属含有酵素<特集>)
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概要
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During the last several years, attempts to furnish the environment (ligand) of metal complexes with chirality-recognizing function, one of the most important features of enzymes, have led to the development of highly enantioselective catalysts (up to 96%ee) which catalyze various reactions involving hydrogenation, hydrosilylation, hydroformylation, codimerization, cross coupling, cyclopropanation, and kinetic resolution. These attempts are reviewed on the type of the information carriers, and some aspects are discussed for designing excellent catalysts with a higher enantioselectivity and catalytic activity.
- 社団法人 有機合成化学協会の論文