固定化金属錯体の有機合成への応用 (有機合成のための反応の場<特集>)

概要

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Immobilization of homogeneous metal complexes were reviewed from the viewpoint of utilization of metal complexes as catalysts of organic synthesis. The preparation methods of heterogenized homogeneous catalysts were described for polystyrene anchored catalysts linked by a phosphine ligand or by a cyclopentadienyl ligand, ionic polymer attached catalysts, and metal complex catalysts with inorganic support. The characteristics of immobilized metal complex catalysts were explained in terms of easiness for treatment of the catalysts, isolation and stabilization of active sites of a catalyst, and usefullness of multi-functional catalysts. The application of the heterogenized homogeneous catalysts for organic synthesis was described with respects to hydrogenation of olefins and dienes, hydroformylation, dimerization of olefins, and asymmetric hydrogenation with emphasis on the selectivity in the reaction.
社団法人有機合成化学協会の論文