液相酸化法を用いた炭化水素から酢酸エステル類の合成および関連反応

概要

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The synthesis of organic acetates with the liquid-phase oxidation of hydrocarbons by transition metals is reviewed. This article described three reactions, i. e., a side-chain acetoxylation of methylbenzenes, a nuclear acetoxylation of aromatic compounds and an acetoxylation of olefins. According to the function of the transition metals, the reaction was divided into two types; a direct activation and an indirect activation of a substrate by the transition metals. In the former, the co-ordination of a substrate and oneelectron-transfer are included. The metal ions in the latter act as an oxidizing agent of halogen ions to its active species which reacts with a substrate to the acetate.<BR>On the basis of the distribution of the reactions, the action of the transition metals in an individual reactin was discussed.
社団法人有機合成化学協会の論文