MA法を応用した酸化物分散強化Ni粉の製造とその特性

概要

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Oxide dispersion strengthened nickel powders containing fine Al2O3, ZrO2 or Y2O3 particles as the dispersoids were prepared by mechanical alloying of carbonyl nickel powders with Al-, Zr- or Y-alkoxide in the air atmosphere followed by heat-treatment in a hydrogen atmosphere at 600°C. The powders thus obtained were then consolidated by compacting and sintering at temperatures from 600°C to 1200°C in a hydrogen atmosphere. Results obtained were as follows: 1) The microstructure of each powder obtained was very fine, and the crystallite sizes of them were in the range of 35nm to 71nm. 2) Among these powders, only Ni-Al2O3 powder showed superior sinterability. The 0.2% -bending strength of the specimen obtained by sintering this powder at 1200°C was 870MPa, which was more than eight times as high as that of the specimen obtained by sintering pure nickel powder. 3) In the case of Ni-Al2O3 powder, sintering began to proceed rapidly in the temperature region where losing the coherency between matrix and Al2O3 particles were significant.
社団法人粉体粉末冶金協会の論文