On second virial coefficients of gases and gas mixtures.
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概要
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Molar refraction and molar polarization were used as new third parameters to correlate the second virial coefficients of nonpolar and polar gases, and their mixtures. A set of consistent data from the compilation of Dymond and SmithSP6) was used for the source data. The correlation was compared extensively with the correlations of Tsonopoulos, Tarakad-Danner, Brewer, Kubic and Vetere. In addition to the new third parameter, the utility of Pitzer''s acentric factor was also tested. The correlation developed was of the general type BPc/RTc=f(0)T/Tc)+κ•f(1)T/Tc) (1)Where κ is the third parameter.
- 公益社団法人 化学工学会の論文
著者
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Tanaka Yuji
Department Of Applied Chemistry Faculty Of Engineering Kyushu Institute Of Technology
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VISWANATH DABIR
Department of Chemical Engineering, University of Missouri-Columbia
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TANAKA YUJI
Department of Chemical Engineering, University of Missouri-Columbia
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