Constant-wavelength neutron diffraction study of cubic perovskites BaTaO2N and BaNbO2N

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概要

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• Local structural disorder of perovskite oxynitrides BaTaO2N and BaNbO2N is investigated by constant-wavelength neutron powder diffraction measurements at 300 and 6 K. Temperature-dependent diffraction line-broadening analyses together with the Rietveld refinements confirm that both perovskites retain average structures of simple cubic symmetry down to 6 K. While the Ta and Nb atoms in the above oxynitrides have remarkably large displacement parameters, indicative of pronounced octahedral distortions, the rigidity of Ba sublattice seems to suppress the cooperative propagation of long-range octahedral tilting.

• 公益社団法人 日本セラミックス協会の論文

著者

• Kim Young-il

  Department Of Metallurgical Engineering Hanyang University

• LEE Eunhye

  Department of Chemistry, Yeungnam University

• KIM Young-Il

  Department of Chemistry, Yeungnam University

• KIM Young-Il

  Department of Chemistry, Center for Molecular Catalysis, Seoul National University

関連論文

• Constant-wavelength neutron diffraction study of cubic perovskites BaTaO2N and BaNbO2N
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