Relation between oxygen concentration in AlN lattice and thermal conductivity of AlN ceramics sintered with various sintering additives
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概要
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Aluminum nitride (AlN) ceramics were fabricated by pressureless sintering with various sintering additives such as 5 mass % Y2O3, 2 mass % Y2O3–3 mass % Al2O3, 3 mass % Y2O3–1 mass % CaO–0.08 mass % B, and 6 mass % Y2O3–2 mass % CaO–0.16 mass % B. The relative density, phases present, lattice parameter c, and thermal conductivity of the samples were evaluated. The oxygen concentration in AlN lattice was estimated from the lattice parameter c by using the relation between the oxygen concentration and the lattice parameter c of AlN. To analyze the effects on the thermal conductivity of the samples, we plotted the oxygen concentration in AlN lattice estimated from the lattice parameters c versus the thermal resistivity, which is inverse of the thermal conductivity measured in this work. The data of the samples sintered with 5 mass % Y2O3 and 3 mass % Y2O3–1 mass % CaO–0.08 mass % B located on the plot of the relation between oxygen concentration in AlN lattice and thermal resistivity of AlN presented by Slack (Slack’s line) or Harris et al. (Harris’s line), respectively. In contrast, the data of the samples sintered with 2 mass % Y2O3–3 mass % Al2O3 and 6 mass % Y2O3–2 mass % CaO–0.16 mass % B, which contain excess grain boundary phases, located above the Harris’s line. It was suggested that the thermal conductivity of the samples could be influenced by the density, the oxygen content in AlN lattice, and the presence of grain boundary phases.
著者
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Imamura Makoto
Department Of Internal Medicine Public Tomioka General Hospital
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Kobayashi Ryota
Department Of Medicine And Molecular Science Gunma University Graduate School Of Medicine
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Oh-ishi Katsuyoshi
Department Of Applied Chemistry Faculty Of Science And Engineering Chuo University
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MORIYA Yoshiaki
Department of Communications Engineering, School of Engineering
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OOSAWA Kazuhiro
Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University
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Kobayashi Ryota
Department Of Applied Chemistry Faculty Of Science And Engineering Chuo University
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Moriya Yoshiaki
Department Of Communications Engineering
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OH-ISHI Katsuyoshi
Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University
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MORIYA Yoshiaki
Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University
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IMAMURA Makoto
Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University
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KOBAYASHI Ryota
Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University
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