Stereochemical Effects in Chemical Ionization Mass Spectrometry Using Chiral Reagent Gases
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概要
- 論文の詳細を見る
The gas chromatographic resolution of isoborneol and borneol enantiomers were achieved by capillary column coated with chiral stationary phase. The gas chromatography/chemical ionization mass spectrometry (GC/CIMS) were performed using (S)-(+)-1-amino-2-propanol, (R)-(−)-1-amino-2-propanol, (S)-(+)-2-amino-1-propanol, and (R)-(−)-2-amino-1-propanol as chiral reagent gases. The CI mass spectra could be obtained with good reproducibilities. It was found that the CI mass spectra of the enantiomers could be distinguished when a chiral reactant ion attached to a chiral functional group of the sample molecule.
- 日本質量分析学会の論文
著者
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Hashimoto K
Kyoto Pharmaceutical University
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Hashimoto Keiji
Nagahama Institute Of Bio-sciences And Technology
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OKAMURA Kimio
Organic Chemistry Research Laboratory, Tanabe Seiyaku Co., Ltd.
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SUMIDA Yoshio
Kyoto Pharmaceutical University
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TERADA Syunji
Kyoto Pharmaceutical University
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HASHIMOTO Keiji
Kyoto Pharmaceutical University
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HASHIMOTO Keiji
Kyoto College of Pharmacy
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