Crystallization Behaviors of Mold Fluxes Containing Li2O Using Single Hot Thermocouple Technique
スポンサーリンク
概要
- 論文の詳細を見る
Minor addition of Li2O (<2 mass%) can significantly alter the melting temperature and viscosity of a mold flux. However, the crystallization tendency of mold fluxes containing Li2O more than 2 mass% hasnt been understood. In this paper, single hot thermocouple technique, X-ray diffraction, and Back Scattered Electron (BSE) were employed to investigate the crystallization behavior concerned with CCT and TTT diagrams of mold fluxes containing high content of Li2O.The critical cooling rate and crystallization rate of samples were increased with the addition of Li2O, whether there is Na2O or not. But the incubation time was reduced obviously with Li2O more than 6 mass% in mold fluxes. The critical cooling rate and incubation time of NL1.5 sample (Na2O=8 mass%, Li2O=1.5 mass%) were close to those of L7 sample (Na2O=0 mass%, Li2O=7 mass%). Moreover, there is no difference in the crystal phase of the two samples, and the crystal phases precipitated at high temperature and low temperature were respectively Ca2(SiO4) and Ca4Si2O7F2. Li-cuspidine was promoted to precipitate when the basicity of the sample was increased. The small, dense grains of cuspidine were observed in NL1.5 sample, and the thickness of slag film was 0.4 mm more than that of L7 sample. The heat flux of NL1.5 sample measured was 10% less than that of L7 sample, as expected. Therefore, high content of Li2O can be substituted by the combination of Na2O and minor of Li2O, as is the composition in the commercial mold fluxes.
論文 | ランダム
- 家畜生産におけるLCA : 肉牛生産を中心にした問題の整理
- 斜め空中写真法による乳牛群の社会・空間分布行動の解析
- 斜め空中写真法による乳牛群の社会・空間分布行動の解析
- 1994年の猛暑が地域の牛乳生産に及ぼした影響とその評価
- 28pYE-1 超音波を利用したヘリウムの結晶成長 : 核生成、島と穴の生成と緩和(領域9,領域6合同招待講演)