Stability of H_2-Permeselective Ni-doped Silica Membranes in Steam at High Temperature

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概要

• 論文の詳細を見る

• Ni-doped silica membranes of various Ni contents (Si/Ni = 0–1/1) were prepared on porous SiO2–ZrO2 composite intermediate layers (Si/Zr = 1/1) by the sol-gel techniques to test their hydrothermal stability and gas permeation characteristics in steam at high temperatures (steam: 90–400 kPa, 500°C). Preceding firing of the intermediate layer and the Ni-doped silica layer in steam at higher temperatures (steam: 90 kPa, 650°C) before exposed to hydrogen at high temperatures was found to drastically improve the hydrothermal stability of Ni-doped silica membranes in steam, showing, for example, a steady permeance of He around 1.7 × 10–5 [m3(STP)·m–2·s–1·kPa–1] with high selectivity of 1150 (He/N2) in steam (steam: 90 kPa, 500°C), which did not change largely even in steam of higher pressure (steam: 400 kPa, 500°C). It was also found that the membrane selectivity could be further improved with negligible decrease in H2-permeance by firing the membranes after impregnating dilute aqueous NiNO3 solution.

• 社団法人 化学工学会の論文
• 2005-11-01

著者

• Asaeda Masashi

  Chemical Engineering Department Graduate School Of Engineering Hiroshima University

• KANEZASHI Masakoto

  Chemical Engineering Department, Graduate School of Engineering, Hiroshima University

• Kanezashi Masakoto

  Chemical Engineering Department Graduate School Of Engineering Hiroshima University

関連論文

• Stability of H_2-Permeselective Ni-doped Silica Membranes in Steam at High Temperature
• Pervaporation of Aqueous Organic Acid Solutions by Porous Ceramic Membranes

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