A Mononuclear Peracetatoiron(III) Complex: Structural and Spectroscopic Characterization, and Oxidation Reactivity
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概要
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A mononuclear peracetatoiron(III) complex [Fe(6Me2-BPP)(CH3C(O)O2)]+ (2) with a tripodal ligand (6Me2-BPP) was prepared in the reaction of an iron(II) complex [Fe(6Me2-BPP)(H2O)]+ (1) with peracetic acid. 2 is the first example of a structurally and spectroscopically well-defined non-heme type peracetatoiron(III) complex and has modest oxidation ability toward triphenyl phosphine, some olefins, and the tertiary C–H bond of adamantane.
- The Chemical Society of Japan = 日本化学会の論文
The Chemical Society of Japan = 日本化学会 | 論文
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