Influence of grain size and surface condition on minority-carrier lifetime in undoped n-BaSi2 on Si(111)

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We have fabricated approximately 0.5-μm-thick undoped n-BaSi2 epitaxial films with various average grain areas ranging from 2.6 to 23.3 μm2 on Si(111) by molecular beam epitaxy, and investigated their minority-carrier lifetime properties by the microwave-detected photoconductivity decay method at room temperature. The measured excess-carrier decay curves were divided into three parts in terms of decay rate. We characterized the BaSi2 films using the decay time of the second decay mode, τ SRH, caused by Shockley-Read-Hall recombination without the carrier trapping effect, as a measure of the minority-carrier properties in the BaSi2 films. The measured τ SRH was grouped into two, independently of the average grain area of BaSi2. BaSi2 films with cloudy surfaces or capped intentionally with a 3 nm Ba or Si layer, showed large τS RH (ca. 8 μs), whereas those with mirror surfaces much smaller τS RH (ca. 0.4 μs). X-ray photoelectron spectroscopy measurements were performed to discuss the surface region of the BaSi2 films.
American Institute of Physicsの論文