Transition metal-catalyzed borylation of alkanes and arenes via C-H activation
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概要
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Since 1999, direct borylation of hydrocarbons catalyzed by a transition metal complex has been extensively studied by severalgroups and has become an economical, efficient, elegant, and environmentally benign protocol for the synthesis of a variety oforganoboron compounds. Re-, Rh-, Ir- and Pd-catalyzed C -H borylation of alkanes, arenes and benzylic positions of alkylarenesby bis(pinacolato)diboron or pinacolborane provide alkyl-, aryl-, heteroaryl- and benzylboron compounds, respectively. In thisreview, seminal early works and exciting recent developments in the area of direct borylation of hydrocarbons via C -H activationare summarized.
- Elsevierの論文
- 2003-08-29
Elsevier | 論文
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