On the cyclization mechanism of squalene : a ring expansion process of the five-membered D-ring intermediate
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Site-directed mutagenesis experiments with W169F, W169H and W489F for the squalene-hopene cyclase, and the formation of 10 possessing the five-membered D-ring and a tetrahydrofuran moiety as the enzyme product of the analogue 8 with a hydroxy group, strongly suggest that a ring expansion reaction from the five- to the six-membered ring is responsible for the D-ring formation of hopene.
- Royal Society of Chemistryの論文
Royal Society of Chemistry | 論文
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