1,4-Asymmetric reduction of γ-keto sulfoxides bearing the 2,4,6-triisopropylphenyl group
スポンサーリンク
概要
- 論文の詳細を見る
Reduction of γ-keto sulfoxides bearing the 2,4,6-triisopropylphenyl group with DIBAL gives γ-hydroxy sulfoxides with high stereoselectivity in the ratio 95:5. In comparison with the lower stereoselectivities obtained in the reaction of γ-keto sulfoxides bearing p-tolyl or 2,4,6-trimethylphenyl groups, the sterically bulky (2,4,6-triisopropylphenyl)-sulfinyl group is extremely efficient in effecting high 1,4-remote asymmetric induction.
- Royal Society of Chemistryの論文
- 2000-09-06
Royal Society of Chemistry | 論文
- Reactions of excited-state benzophenone ketyl radical in a room-temperature ionic liquid
- Ultrathin tough double network hydrogels showing adjustable muscle-like isometric force generation triggered by solvent
- Motion of methanol adsorbed in porous coordination polymer with paramagnetic metal ions
- Hyperbranched 5,6-glucan as reducing sugar ball
- Stereoselective tris-glycosylation to introduce β-(1→3)-branches into gentiotetraose for the concise synthesis of phytoalexin-elicitor heptaglucoside