Photoluminescence quenching in cobalt doped ZnO nanocrystals

概要

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Influence of cobalt doping on the luminescence properties of ZnO nanocrystals with average diameter of 3.0 nm is investigated. Time resolved measurements at 20 K show that the dark exciton luminescence is completely lost in the nanocrystals doped with cobalt, while the perturbed luminescence with slight red shift survives and exhibits a non-exponential decay curve reflecting random distribution of cobalt atoms. By analyzing the non-exponentiality, the increase of the decay rate of the band-edge luminescence induced by the inclusion of single cobalt atom is estimated to be 0.012 ps-1
2012-05-07