CO2 光還元複核金属錯体触媒系の開発

概要

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A new bipyridine derivative bearing a perylene unit, mono-imide of Tetrabromoperylene tetrabarboxylic anhydride with 4-aminobipyridine, was prepared as a ligand to develop new multinuclear complexes for CO2 photoreduction. The perylene unit was chosen for a wider absoption band of a visible light and a long-lived excited state.Tetrabromoperylene tetrabarboxylic anhyderide was shown to be a promising candidate for higher solubility of thebipyridine ligand and also the Ru complexes.