遷移金属錯体触媒を用いる効率的・選択的合成反応の研究
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概要
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The thermal reaction of a (dibenzobarreleneselenolato)(hydrido)platinum(II) complex gave twofour-membered selenaplatinacycles, one of which is formed by hydroplatination of the Pt-H bond to the etheno bridge and the other is a vinylic C-H bond activation. The reaction mechanism for the cyclometalation is investigated.