Nickel(II) complexes bearing a pincer ligand containing thioamide units: Comparison between SNS- and SCS-pincer ligands
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概要
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Nickel(II) complexes bearing a κ3SNS pincer ligand, 2,5-bis(benzylaminothiocarbonyl)pyrrolyl (L1) and a κ3SCS-pincer ligand, 2,6-bis(benzylaminothiocarbonyl)phenyl (L2), were synthesized, and their structures and electrochemical properties were elucidated. The crystal structures of [Ni(SNS)Br] (2) and [Ni(SCS)Br] (5) were determined by X-ray crystallography. The electrochemical and crystallographic data obtained from the complexes revealed that the κ3SCS ligand has a stronger electron-donating ability than the κ3SNS ligand.
- 2010-08-10
論文 | ランダム
- 子どもの連続量保存の認識
- 子どもの図形認識 : 特に,図形の模写能力と選別能力,模写能力の成長率を中心として(その2)
- 子どもの図形認識 : 特に,再生調査(描画調査)を中心として(その1)
- 子どもの系列的対応づけなどの諸様相
- 9. 全体と部分の認識 : とくに,類の加法的合成について (大学部会)