Synthesis and Characterization of Poly[(benzo[1,2-d:5,4-d']bisthiazole-2,6-diyl)-1,4-phenylene]
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Poly[(benzo[1,2-d:5,4-d']bissthiazole-2,6-diyl)-1,4-phenylene](cis-PBZT)with a relatively high molecular weight was prepared by a new synthesis route. Properties of the synthesized polymer, such as thermostability, liquid crystallinity etc. were investigated and compared with those of trans-PBZT. cis-PBZT was crystallized from dilute solution and the electron microscopy showed that the precipitate was a rod-like crystal similar to that of trans form. In spite of rigid nature of the back bone, cis-PBZT showed poor crystallinity.
- Faculty of Engineering, Okayama Universityの論文
- 1996-12-27
Faculty of Engineering, Okayama University | 論文
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