Robust Existence of a Reaction Boundary to Separate the Fate of a Chemical Reaction
スポンサーリンク
概要
- 論文の詳細を見る
Nonlinear dynamics around a rank-one saddle is investigated in a high energy regime above the reaction threshold. The transition state (TS) is considered as a surface of a "point of no return" through which all reactive trajectories pass only once in the process of climbing over the saddle before being captured in the product state. A no-return TS ceases to exist above a certain high energy regime. However, even at high energies where the no-return TS can no longer exist, it is shown that "an impenetrable barrier" in the phase space robustly persists, which acts as a boundary between reactive and nonreactive trajectories. This implies that we can yet predict the fate of reactions even when the no-return TS may not exist. As an example, we show the analysis of dynamical systems theory for a hydrogen atom in crossed electric and magnetic fields.
- 2010-07-23
論文 | ランダム
- 2 社会調査の現状とその問題点(II 教育心理学研究における因果関係の同定,研究委員会企画シンポジウム)
- スポーツテストの比較的研究
- シングルチップマイコン用構造化アセンブラ (半導体デバイス特集) -- (シングルチップマイクロコンピュ-タについて)
- マイクロコンピューター用ソフトウェアの動向
- オ-バ-レイ・テクニック (′80年版マイクロコンピュ-タ導入設計ガイド) -- (実践的なポイントアドバイス)