Direct synthesis of Cryolite type Li3FeF6 and its characterization as positive electrode in Li cell
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概要
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We have synthesized a Cryolite type iron hexafluoroferrates by mild chemistry complex formation reaction. For the first time their electrochemical properties as positive electrode materials in rechargeable batteries were studied. The alpha-Li3FeF6 delivered a 116 mAh/g reversible capacity at an average discharge voltage of 3.0 V maintaining good capacity retention of about 30 cycles at a 0.2 mA/cm2 rate. The preliminary results are reported.
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