結晶化による有機化合物の光学分割法の開発とその応用に関する研究<総説マイレビュー>

概要

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Some new methods and practical strategies for the efficient resolution of a wide variety of organic compounds by means of such crystallization procedures as preferential crystallization, diastereomeric salt formation and their combination are described. Utilizing the organic compounds with high optical purities thus obtained, application study in the follwing field has been performed; 1) verification of the Brewster's theory of optical activity, 2) syntheses of pharmaceutical, agricultural and perfuming chemicals, 3) preparation of optical purity determining agents, 4) preparation of atropisomeric bis (triarylphosphine) as a catalyst for asymmetric hydrogenation, 5) syntheses of ferroelectric liquid crystals.
埼玉大学分析センターの論文