Electrochemical properties of alkali bis(trifluoromethylsulfonyl)amides and their eutectic mixtures
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概要
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Densities, viscosities and ionic conductivities of single salts and the binary eutectic mixtures of alkali bis(trifluoromethylsulfonyl)amides, MTFSAs (M = Li, Na, K, Rb, Cs), were measured in the temperature range of 413-573 K. Cyclic voltammetry revealed that the binary eutectic melts have wide electrochemical windows of 5.0-6.0 V. It was found that alkali metals reversibly deposit on a nickel electrode at the cathode limit potentials. The order of the deposition potential was determined to be Na > Li > (K, Rb, Cs).
- 2010-01-01
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