組織分子膜における機能性原子団の配列制御<総説 レビュー>
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概要
- 論文の詳細を見る
Monolayer assemblying methods provide a well-defined and planned organization of amphiphilic molecules with functional groups in layered structures. Prior to fabrication of the molecular organization, control of molecular orientation and packing as well as domain structures and sizes in monolayers on the water surface were studied. Molecular recognition, inclusion and adsorption of functional molecules by lipids or CDs monolayers at the air/water interface have been also valid to control the molecular arrangements. The monolayer assemblies could be fabricated by the horizontal-lifting or the surface-lowering, and the Langmuir-Blodgett (vertical-dipping) methods to give the non-alternating X-type or Z-type, and the alternating Y-type films. Some characteristics of optical and electrical bahaviors for these organized molecular films with functional groups have been discussed, and also effects of the molecular orientation and packing upon the chemical reactions at the interfacial films have been considered.
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