Photoluminescence enhancement and quenching of single CdSe/ZnS nanocrystals on metal surfaces dominated by plasmon resonant energy transfer

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We studied the mechanism of the photoluminescence (PL) enhancement and quenching of single CdSe/ZnS nanocrystals on rough Au surfaces. Single nanocrystal spectroscopy revealed that the PL enhancement depends strongly on the excitation wavelength and liner-polarization angle due to the localized plasmon excitation and is also sensitive to the nanocrystal size. The polarization- and size-dependent PL enhancement and quenching are determined by the balance between the resonant energy transfer from the nanocrystal to the Au surface and the electric field enhancement.