示差走査熱量測定による構造相転移と融解の研究(2)

概要

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Differential scanning calorimetry (DSC) was measured on [C(NH_2)_3] Cd_2Br_5, (4-CH_3C_5H_4NH)_2ZnBr_4, [2, 6-(CH_3)_2C_5H_4NH]_2ZnBr_4, and [C(NH_2)_3]_2ZnBr_4 between about 130 K and theirmelting points. (4-CH_3C_5H_4NH)_2ZnBr_4 and [C(NH_2)_3]_2ZnBr_4 showed no structural phasetransition, while [C(NH_2)_3]Cd_2Br_5 and [2, 6-(CH_3)_2C_5H_3NH]_2ZnBr_4 showed some transitions.Furthermore, these crystals exhibited some unusual DSC results. This paper reports onthese unusual points.
琉球大学理学部の論文