Oxygen Exchange at the Internal Surface of Amorphous SiO2 Studied by Photoluminescence of Isotopically Labeled Oxygen Molecules

概要

論文の詳細を見る
The exchange between lattice and interstitial oxygen species in an oxide was studied by the 16O-18O isotope shift of the a1Deltag(v=0)-->X3Sigma<sub>g</sub><sup>-</sup>(v=1) infrared photoluminescence band of the oxygen molecules (O2) incorporated into the interstitial voids of amorphous SiO2 (a-SiO2) by thermal annealing in 18O2 gas. A large site to site variation of the oxygen exchange rate, originating from structural disorder of a-SiO2, is found. The average exchange rate has an activation energy of ~2 eV, which is much larger than that for the diffusion of interstitial O2 (~0.8–1.2 eV). The average exchange-free diffusion length of interstitial O2 exceeds ~1 µm below 900 °C, providing definite evidence that oxygen diffuses as interstitial molecules in a-SiO2.