New anti-fluorite solid-solution phases in Li-Ti-N ternary system
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概要
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New Li-Ti-N solid-solution compounds with an anti-fluorite-type superstructure were synthesized by heating the mixture of Li_3N and TiN at 800℃ in Ar flow. The compositions of the new compounds seem to lie on the tie-line between the two wellknown compounds, Li_3N (hexagonal, P6/mmm) and Li_5TiN_3 (cubic, I2_1/a-3) by Li evaporation during heating in Ar gas flow, and nominally represented with Li_<5+y>Ti_<1-y>N_<3-y>. The solubility is large; the anti-fluorite-type superstructure of Li_5TiN_3 (y=0) was retained up to y=ca. 0.9, which is close to the end member Li_3N (y=1) with a different layered structure. This finding opens up further exploring other new Li-M-N (M= transition metals, group XIII, or XIV elements) phases with some attractive functions.
- 2009-01-01
著者
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Mori Shunsuke
Department of Cardiology Kumamoto Chuo Hospital
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Kanno Ryoji
Department Of Electronic Chemistry Interdisciplinary Graduate School Of Science And Engineering Toky
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Kanno Ryoji
Department Of Chemistry Faculty Of Science Kobe University
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Mori Shunsuke
Department Of Electronic Chemistry Interdisciplinary Graduate School Of Science And Engineering Toky
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YAMADA Atsuo
Department of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, To
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IYAMA Hiromasa
Department of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, To
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SHIBATA Masatoshi
Functional Materials Laboratory, Central Research Laboratories, Idemitsu Kosan Co., Ltd.
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Yamada Atsuo
Department Of Electronic Chemistry Interdisciplinary Graduate School Of Science And Engineering Toky
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Iyama Hiromasa
Department Of Electronic Chemistry Interdisciplinary Graduate School Of Science And Engineering Toky
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Shibata Masatoshi
Functional Materials Laboratory Central Research Laboratories Idemitsu Kosan Co. Ltd.
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