CeCl_3水溶液からの単結晶性CeO_2ナノロッドの簡易合成(<特集>水溶液科学に立脚したセラミックス合成プロセス)

スポンサーリンク

概要

• 論文の詳細を見る

• Fluorite-type CeO_2 nanorods were synthesized from aqueous CeCl_3 solutions containing polyethylene glycol, NaOH, and NaCl. The solutions were hydrothermally treated at 140℃, resulting in the formation of nanorod-like precipitates. Further annealing of the precipitates led to the growth into, well-defined nanorods 5-10nm in diameter and 50-200nm in length. It was found that the addition of NaCl to the solution could enhance the one-dimensional growth of CeO_2 and reduce the degree of aggregation. A high-resolution transmission electron microscopic observation revealed that the nanorod was single-crystalline and its growth direction was along the [110] axis of the cubic CeO_2 structure. Our results then demonstrated that the unusually [110]-oriented CeO_2 nanorods could be grown by a facile synthesis method.

• 社団法人日本セラミックス協会の論文
• 2007-12-01

著者

• 藤原 忍

  Department Of Applied Chemistry Faculty Of Science And Technology Keio University

• 東根 泰葉

  Department of Applied Chemistry, Faculty of Science and Technology, Keio University

• 東根 泰葉

  Department Of Applied Chemistry Faculty Of Science And Technology Keio University

関連論文

• CeCl_3水溶液からの単結晶性CeO_2ナノロッドの簡易合成(水溶液科学に立脚したセラミックス合成プロセス)

スポンサーリンク