Reaction between Lipid Hydroperoxide and Hemoglobin Studied by a Spectrophotometric and a Spin Trapping Method(Biological Chemistry)
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概要
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The reaction between lipid hydroperoxide and hemoglobin (Hb) under aerobic condition was studied kinetically by a spectrophotometric and a spin trapping method. The reaction did not follow simple first order or second order kinetics, possibly because Hb was also decomposed during the decomposition of lipid hydroperoxide. A spin trap reagent decreased the rate of the reaction. Some free radicals were trapped by the spin trap reagent and their structures were found from ESR spectra of spin adducts. These results were explained by a free-radical chain reaction mechanism initiated by lipid hydroperoxide and Hb.
- 社団法人日本農芸化学会の論文
- 1986-07-23
著者
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YOSHIDA YASUSHI
Department of Surgery, Kumamoto Rosai Hospital
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Yoshida Y
Kinki Univ. Higashi‐osaka Jpn
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TANIGUCHI Hitoshi
Department of Physical Electronics, Tokyo Institute of Technology
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AOSHIMA Hitoshi
Department of Chemistry, Faculty of Liberal Arts Yamaguchi University
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Aoshima Hitoshi
Department Of Chemistry Faculty Of Liberal Arts Yamaguchi University
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Aoshima Hitoshi
Department Of Biology Physics And Informatics Faculty Of Science And Department Of Biological Chemis
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Taniguchi Hitoshi
Department Of Chemistry Faculty Of Liberal Arts Yamaguchi University
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Yoshida Yasushi
Department Of Medicine Division Of Hypertension And Cardiorenal Disease Dokkyo University School Of
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YOSHIDA Yasushi
Department of Chemistry, Faculty of Science, Yamaguchi University
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