Effect of Chemical Property of Waste Biomass on Air-Steam Gasification
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概要
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Air-steam gasification of waste biomass was performed using a downdraft-fixed gasifier at atmospheric pressure and 1173K. The effect of a chemical property of waste biomass feedstock on the product distribution and product gas composition was statistically investigated. Twelve types of waste biomass and three types of model compounds of woody biomass were employed as feedstock. Gas, water soluble compound, water insoluble-acetone soluble compound, acetone insoluble compound, and char were obtained as products. Regardless of the variety of feedstock, the volatile matter content was the factor affecting the distribution to gas and product gas composition. The distribution to gas, i.e., the conversion to gas on a carbon basis, increased from 52.8 to 97.9 C-mol% with an increase in the volatile matter content in the feedstock. The distributions to the water soluble compound, water insoluble-acetone soluble compound, and acetone insoluble compound were independent of the chemical property, and would be affected by the nitrogen and ash contents in the feedstock. The main product gas was H_2 (20-35 mol%), CO (15-30 mol%), CO_2 (20-35 mol%), and CH_4 (5-10 mol%). When the volatile matter content was more than 70 wt%, the molar ratio of H_2 to CO in the product gas (H_2/CO) decreased with an increase in the volatile matter content, while the molar ratio of H_2 to CO_2 (H_2/CO_2) was approximately unity and independent of the chemical property. In waste biomass with a volatile matter content of 70-80 wt%, syngas with the desired H_2/CO ratio for methanol synthesis was obtained. In waste biomass with a volatile matter content of more than 80 wt%, syngas with the desired H_2/CO ratio for dimethyl ether (DME) synthesis was obtained.
- 一般社団法人日本エネルギー学会の論文
- 2005-12-20
著者
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MINOWA Tomoaki
Biomass Technology Research Center, National Institute of Advanced Industrial Science and Technology
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HANAOKA Toshiaki
Biomass Division, National Institute for Resource and Environment
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Edashige Yusuke
Department Of Forest Resources Ehime University
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Hanaoka Toshiaki
Biomass Division National Institute For Resource And Environment
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Minowa Tomoaki
Biomass Technology Research Center National Institute Of Advanced Industrial Science And Technology
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MIYAMOTO Atsuko
Department of Forest Resources, Ehime University
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Miyamoto Atsuko
Department Of Forest Resources Ehime University
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Minowa Tomoaki
Biomass Technology Research Center National Institute Of Advanced Industrial Science And Technology
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Hanaoka Toshiaki
Biomass Technology Research Center National Institute Of Advanced Industrial Science And Technology
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