44.ポリアクリルアミドの水溶液物性

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概要

• 論文の詳細を見る

• Intrinsic viscosity [η] in water, light scattering in formamide and GPC in 0.05M KCl aqueous solution were measured for fractionated polyacrylamide, PAAm, samples with a wide range of molecular weights. The effects of temperature and the addition of KCl, CaCl_2 salts on [η] were studied, [η]-molecular weight, M_w, relationship in water at 25.0℃ was obtained as follows: [η]=2.67×10^<-4> M_w^0.66 The value of [η] of PAAm in water was unaffected by the increase in temperature and the addition of KCl and CaCl_2. These results suggest a non-ionic character of PAAm aqueous solutions and the absence of any interaction between polar group in PAAm and neutral salts. In addition, it seems impossible to occur any hydrogen bonding for PAAm aqueous solutions.

• 東京女子大学の論文
• 1978-03-20

著者

• 恩田 宣彦

  東京教育大学理学部化学科

• 平井 康雅

  東京教育大学理学部部化学科

関連論文

• 51.ポリアクリルアミド希薄溶液の非ニュートン粘性
• 44.ポリアクリルアミドの水溶液物性

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