Supramolecular assembly of p-tert-butylthiacalix[6]arene with benzylamine complex based on hydrogen bond

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概要

• 論文の詳細を見る

• It is well known that p-tert-butylthiacalixarenes can make host-guest complexation with organic guest molecules and metal cations. In order to study crystal structural properties of the host molecule with organic compounds, we tried to make a new crystal of the p-terf-butylthiacalix [6] arene with benzylamine. Treatment of thiacalix [6] arene with excess of benzylamine afforded the complex of thiacalix [6] arene with 8 molecules of benzylamine as crystals, which shows highly-extensive hydrogen bonded between host and guests to give rise to supramolecular assembly. The structure of thiacalix [6] arene as a host is 1,2,3-alternate with 4 molecules benzylamine as inner guests and the other 4 molecules of benzylamine locate outside of thiacalix [6] arene.

• 秋田大学の論文

著者

• KONDO Yoshihiko

  Faculty of Engineering and Resource Science, Akita University

• Hamada Fumio

  Akita University

• KONDO Yoshihiko

  Akita University

• Hamada Fumio

  Akita Univ. Akita Jpn

• Kondo Yoshihiko

  Akita Univ. Akita Jpn

関連論文

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• Discharge Property of Resin Particles Refined by Silica Particles : Atoms, Molecules, and Chemical Physics
• Supramolecular assembly of p-tert-butylthiacalix[6]arene with benzylamine complex based on hydrogen bond
• Supramolecular Assembly Based on 9,10-bis(3,5-clihyclroxy-1-phenyl)Anthracene-tetrakis β-cyclodextrin with Guest Molecule

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