Surface Bond between Organic Corrosion Inhibitors and Metal Surfaces

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概要

• 論文の詳細を見る

• The delocalization energy in the surface bond formation is estimated by the method proposed by Grimley, using a linear crystal model and the "tight-binding" approximation. The change of the energy with the electronegativity of a foreign atom and a surface metal atom is discussed. The change of polarization of electrolytic iron and pure nickel by the addition of an inhibitor in dilute mineral acids is in general agreement with the theoretical deduction attained on the assumption that the surface bond is formed by over-lapping of a lone pair electron orbital of an inhibitor molecule and a vacant orbital of a surface metal atom.

• 東北大学の論文

著者

• Suetaka Wataru

  The Research Institute For Iron Steel And Other Metals

• Shimodaira Saburo

  The Research Institute For Iron Steel And Other Metals

関連論文

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• Dezincification of Alpha Brass
• Stress-Corrosion Cracking in Austenitic Stainless Steel under Constant Strain Rate and Constant Polarization
• Surface Bond between Organic Corrosion Inhibitors and Metal Surfaces
• Study on the Corrosion Resistivity of Al-Mg Alloys by means of a Potentiostat
• On the Electrochemical Behaviors of Copper-Gold Alloys
• On the Mechanism of the Rebinder Effects in MgO Immersed in N,N-Dimethylformamide and/or Dimethylsulfoxide
• Far Infra-Red Absorption Spectra of Ferric Oxides and Oxyhydroxides
• The Absorption Spectra of Thiourea and Potassium Iodide on Nickel Metal

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