Vibrations of Tropylium Ion
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概要
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Assuming the D_<7h> symmetry to the tropylium ion, its vibrations have been calculated after the Crawford type treatment. Two ways of the calculation have been adopted, one was based on the frequencies observed by Lippincott and the other on the force constants derived from benzene's value. The former treatment gave a set of force constants that fitted well with the observed frequencies. The latter followed the frequencies that fitted with the observed ones within 5 percent except two cases. Moreover, using the latter method, the inactive vibrations were calculated and predicted.
- 東北大学の論文
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