レーザマイクロプローブアナライザによる岩石の定量分析

概要

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A quantitative elemental analysis of silicate rocks was carried out with a laser microprobe analyzer. A Q-switched Nd:YAG laser (90mJ, 10ns) was focused on rock samples in an argon atmosphere at reduced pressure, and the emission spectra from laser-induced plasma were measured using time-resolved spectroscopy. The experimental results showed that the maximum spectral line intensity was obtained in argon at approximately 200Torr, whereas the spectral line-to-background ratio was maximized at around 60Torr, by observing the laser plasma with a time delay of 0.4μs. Furthermore, the results of time-resolved spectroscopy of the plasma produced in argon at 200Torr and 60Torr indicated that time-resolved measurement of a spectrum in the initial stage of plasma generation (〜l|μs) at a pressure of 60Torr was effective for improving the slope of the calibration curve. Based on the results, standard rock samples were analyzed for aluminum, magnesium and calcium, and linear calibration curves with a slope of unity were obtained by measuring spectra with a gate width of 0.6μs at a delay time of 0.4μs after the laser pulse in argon at 60Torr.
中部大学の論文
2003-12-15