Preparation of Highly Soluble N-Substituted Polyanilines and Their Novel Solvatochromism
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概要
- 論文の詳細を見る
Poly(N-dodecylaniline), poly(N-dodecylaniline-co-aniline) and poly(N-octanoylaniline-co-aniline) were prepared from reduced polyaniline using the elimination reaction of hydrogen halide of 1-bromododecane or octanoyl chloride. They are soluble in several organic solvents. Solvatochromic shifts of spectra of their solutions have been observed and analyzed in terms of various solvent parameters. The linear relationships between the energy of absorption maxima and donor number of solvents or Taft's β parameters have been found, Color changes of solutions are explained by the changes in solute-solvent interactions.
- 社団法人応用物理学会の論文
- 1991-04-01
著者
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Yoshino Katsumi
Department Of Electrical Engineering Faculty Of Engineering Osaka University
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OKA Osamu
Technical Research Laboratory, Tomoegawa Paper Co., Ltd.
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KIYOHARA Osamu
Technical Research Laboratory, Tomoegawa Paper Co., Ltd.
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Kiyohara Osamu
Technical Research Laboratory Tomoegawa Paper Co. Ltd.
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Oka Osamu
Technical Research Laboratory Tomoegawa Paper Co. Ltd.
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Oka Osamu
Functional Material Section, Technical Research Laboratory
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Kiyohara Osamu
Functional Material Section, Technical Research Laboratory
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