Isotope Effect in the 0_2 and S0 Molecules

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概要

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• The rotational energy, spin-orbit coupling, spin-spin coupling, and the coupling between the molecular rotation and the electron spin are taken into account up to the second order perturbation in the Born-Oppenheimer approximation. The resulting expressions of coupling constants, such as B_e, D_e, α, α_D, λ_e, λ_d, λ_<DD>, α_λ, α_<λD>, α_<λDD>, γ_e, γ_D, α_γ, α_<λD>, in the effective Hamiltonian show specific dependences on the reduced mass μ of the diatomic molecule under consideration. The theory is tested for 13 molecular parameters for the 0_2 isotope molecules and 8 molecular parameters for the SO isotope molecules and they all agree with experimental data within the presently available accuracy.

• 社団法人応用物理学会の論文
• 1987-05-20

著者

• MIZUSHIMA Masataka

  Department of Astrophysics, Nagoya University:(Present address) Department of Physics, University of Colorado

関連論文

• Tables Useful for the Calculation of the Molecular Integrals I
• Tables Useful for the Calculation of the Molecular Integrals II
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• Radiation Process as an Adiabatic Process
• Anisotropy of Space
• Electron Spin Resonance of the Oxygen Molecule in Blood
• Gravitational Waves as Anisotropy of Space
• Isotope Effect in the 0_2 and S0 Molecules

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