Quasi-Instantaneous Measurements of Titanium Compunds Using Auger Electron and Auger Electron Appearance Potential Spectroscopies
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概要
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The Auger electron and Auger electron appearance potential spectra of Ti, TiC_x, TiN_x, and TiO_2 were observed quasi-in-stantaneously, and the energy shift values for the L_3M_<2,3>M_<4.5> Auger peak were found to be 1.5 eV, 4.6 eV and 5.3 eV for TiC_x, TiN_x and TiO_2, respectively. These values correspond to the energy separation between band (2e_g→2p_<2/3>) and band (2t_<2g>→2p_<3/2>) in XES (X-ray emission spectra) for TiN or the absorption edge in SXAS (soft X-ray absorption spectra) for TiC and TiO_2. The threshold values of the L_3 AEAP spectra in titanium compounds show good agreement with the energy position of the L_3-absorption edge in SXAS. The energy separation between the main peak and the shoulder peak at high energy for TiN. and TiO_2 in AEAP spectra corresponds to that of empty states in SXAS.
- 社団法人応用物理学会の論文
- 1984-08-20
著者
-
Konishi Ryosuke
Department Of Electrical And Electronic Engineering Tottori University
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Kato Susumu
Department Of Anatomy (1) Jikei University School Of Medicine
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